The rotational spectra of 79Br12C15N and 81Br12C15N in the low-lying 01 10, 1000, 0200, and 0220 vibrational states have been observed in the millimeter-wave region, and the ν3 fundamental band of both 14N- and 15N-containing species has been recorded from 2125 to 2215 cm-1 with a diode laser spectrometer. A very precise equilibrium structure has been calculated for cyanogen bromide using the obtained data together with those already known for the normal isotopomers. The ground state rotational spectra of 79Br13C15N and 81Br13C15N have been also observed, so that r0, rs, and rm structures could be evaluated from the ground state moments of inertia of eight different isotopic species. © 1995 Academic Press, Inc.
Millimeter-wave and infrared spectrum of brc15n: Equilibrium structure of cyanogen bromide / Tamassia F.; Esposti C.D.; Dore L.; Cazzoli G.. - In: JOURNAL OF MOLECULAR SPECTROSCOPY. - ISSN 0022-2852. - STAMPA. - 174:1(1995), pp. 59-77. [10.1006/jmsp.1995.1267]
Millimeter-wave and infrared spectrum of brc15n: Equilibrium structure of cyanogen bromide
Tamassia F.;Dore L.;Cazzoli G.
1995
Abstract
The rotational spectra of 79Br12C15N and 81Br12C15N in the low-lying 01 10, 1000, 0200, and 0220 vibrational states have been observed in the millimeter-wave region, and the ν3 fundamental band of both 14N- and 15N-containing species has been recorded from 2125 to 2215 cm-1 with a diode laser spectrometer. A very precise equilibrium structure has been calculated for cyanogen bromide using the obtained data together with those already known for the normal isotopomers. The ground state rotational spectra of 79Br13C15N and 81Br13C15N have been also observed, so that r0, rs, and rm structures could be evaluated from the ground state moments of inertia of eight different isotopic species. © 1995 Academic Press, Inc.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
