The highly sensitive method of radio-frequency-infrared double resonance inside a CO2 laser is applied to study collision-induced transitions in CH3I in a four-level double resonance scheme. Pure nuclear quadrupole resonances are observed as the result of collision population transfer between different rotational levels. The intensity ratios of the collision-induced dips to the corresponding three-level double resonance signals are measured for a number of transitions in the ground and excited vibrational states. Collision selection rules in the pure gas and in mixtures with polar and non-polar gases are discussed.
Tamassia F., Danieli R., Scappini F. (1999). Collision-induced radio-frequency transitions in CH3I. CHEMICAL PHYSICS LETTERS, 300(3-4), 478-482 [10.1016/S0009-2614(98)01358-X].
Collision-induced radio-frequency transitions in CH3I
Tamassia F.;
1999
Abstract
The highly sensitive method of radio-frequency-infrared double resonance inside a CO2 laser is applied to study collision-induced transitions in CH3I in a four-level double resonance scheme. Pure nuclear quadrupole resonances are observed as the result of collision population transfer between different rotational levels. The intensity ratios of the collision-induced dips to the corresponding three-level double resonance signals are measured for a number of transitions in the ground and excited vibrational states. Collision selection rules in the pure gas and in mixtures with polar and non-polar gases are discussed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.