A dehydrogenative functionalization of styryl carbon-carbon double bonds with triflamide is described via dual visible-light photoredox/cobaloxime catalysis. A range of allylic triflamides (20 examples) were isolated in moderate to good yields (up to 88%) under stoichiometric acceptorless conditions. Dedicated labelling, as well as spectroscopic experiments, enabled to shed light on the concatenated photo- and chemo-catalytic cycles. (Figure presented.).

Battaglioli S., Bertuzzi G., Pedrazzani R., Benetti J., Valenti G., Montalti M., et al. (2022). Visible-Light-Assisted Synthesis of Allylic Triflamides via Dual Acridinium/Co Catalysis. ADVANCED SYNTHESIS & CATALYSIS, 364(4), 720-725 [10.1002/adsc.202101329].

Visible-Light-Assisted Synthesis of Allylic Triflamides via Dual Acridinium/Co Catalysis

Battaglioli S.;Bertuzzi G.;Pedrazzani R.;Valenti G.;Montalti M.;Monari M.;Bandini M.
2022

Abstract

A dehydrogenative functionalization of styryl carbon-carbon double bonds with triflamide is described via dual visible-light photoredox/cobaloxime catalysis. A range of allylic triflamides (20 examples) were isolated in moderate to good yields (up to 88%) under stoichiometric acceptorless conditions. Dedicated labelling, as well as spectroscopic experiments, enabled to shed light on the concatenated photo- and chemo-catalytic cycles. (Figure presented.).
2022
Battaglioli S., Bertuzzi G., Pedrazzani R., Benetti J., Valenti G., Montalti M., et al. (2022). Visible-Light-Assisted Synthesis of Allylic Triflamides via Dual Acridinium/Co Catalysis. ADVANCED SYNTHESIS & CATALYSIS, 364(4), 720-725 [10.1002/adsc.202101329].
Battaglioli S.; Bertuzzi G.; Pedrazzani R.; Benetti J.; Valenti G.; Montalti M.; Monari M.; Bandini M.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/862607
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