Chemoenzymatic oxidations involving the CAL-B/H2O2 system was developed in a sugar derived Natural Deep Eutectic Solvent (NaDES) composed by a mixture of glucose, fructose and sucrose. Good to excellent conversions of substrates like cyclooctene, limonene, oleic acid and stilbene to their corresponding epoxides, cyclohexanone to its corresponding lactone and 2-phenylacetophenone to its corresponding ester, demonstrate the viability of the sugar NaDES as a reaction medium for epoxidation and Baeyer-Villiger oxidation.
Vagnoni, M., Samori', C., Pirini, D., Vasquez De Paz, M.K., Gidey, D.G., Galletti, P. (2022). Lipase catalysed oxidations in a sugar-derived natural deep eutectic solvent. BIOCATALYSIS AND BIOTRANSFORMATION, 40(6), 422-431 [10.1080/10242422.2021.1913126].
Lipase catalysed oxidations in a sugar-derived natural deep eutectic solvent
Vagnoni M.;Samori' C.;Galletti P.
2022
Abstract
Chemoenzymatic oxidations involving the CAL-B/H2O2 system was developed in a sugar derived Natural Deep Eutectic Solvent (NaDES) composed by a mixture of glucose, fructose and sucrose. Good to excellent conversions of substrates like cyclooctene, limonene, oleic acid and stilbene to their corresponding epoxides, cyclohexanone to its corresponding lactone and 2-phenylacetophenone to its corresponding ester, demonstrate the viability of the sugar NaDES as a reaction medium for epoxidation and Baeyer-Villiger oxidation.| File | Dimensione | Formato | |
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EPOSSIDI.pdf
Open Access dal 25/04/2022
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