A new straightforward synthetic strategy has been elaborated to achieve star-shaped triazatrinaphthylene and, for the first time, triazatrianthrylene derivatives. Their solution- and solid-state properties were thoroughly characterized by cyclic voltammetry, UV–vis absorption spectroscopy, X-ray diffraction, and density functional theory calculations. Original hexagonal molecular arrangements were found in the crystal phase, which opens a new pathway for designing materials with improved three-dimensional charge-transport properties.
Li, Q., Moussallem, C., Castet, F., Muccioli, L., Dourges, M., Toupance, T., et al. (2022). Direct Triple Annulations: A Way to Design Large Triazastarphenes with Intertwined Hexagonal Packing. ORGANIC LETTERS, 24(1), 344-348 [10.1021/acs.orglett.1c04001].
Direct Triple Annulations: A Way to Design Large Triazastarphenes with Intertwined Hexagonal Packing
Muccioli, Luca;
2022
Abstract
A new straightforward synthetic strategy has been elaborated to achieve star-shaped triazatrinaphthylene and, for the first time, triazatrianthrylene derivatives. Their solution- and solid-state properties were thoroughly characterized by cyclic voltammetry, UV–vis absorption spectroscopy, X-ray diffraction, and density functional theory calculations. Original hexagonal molecular arrangements were found in the crystal phase, which opens a new pathway for designing materials with improved three-dimensional charge-transport properties.File | Dimensione | Formato | |
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