Two-dimensional fused aromatic networks (2D FANs) have emerged as a highly versatile alternative to holey graphene. The synthesis of 2D FANs with increasingly larger lattice dimensions will enable new application perspectives. However, the synthesis of larger analogues is mostly limited by lack of appropriate monomers and methods. Herein, we describe the synthesis, characterisation and properties of an expanded 2D FAN with 90-ring hexagons, which exceed the largest 2D FAN lattices reported to date.
Riano A., Strutynski K., Liu M., Stoppiello C.T., Lerma-Berlanga B., Saeki A., et al. (2022). An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 61(2), 1-7 [10.1002/anie.202113657].
An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons
Liu M.;Valenti G.;Paolucci F.;
2022
Abstract
Two-dimensional fused aromatic networks (2D FANs) have emerged as a highly versatile alternative to holey graphene. The synthesis of 2D FANs with increasingly larger lattice dimensions will enable new application perspectives. However, the synthesis of larger analogues is mostly limited by lack of appropriate monomers and methods. Herein, we describe the synthesis, characterisation and properties of an expanded 2D FAN with 90-ring hexagons, which exceed the largest 2D FAN lattices reported to date.| File | Dimensione | Formato | |
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Angewandte Chemie Intl Edit - 2021 - Ria o - An Expanded 2D Fused Aromatic Network with 90â Ring Hexagons.pdf
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