Fe-Cu octahedral carbide clusters, and the replacement of their labile halide ligands: syntheis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2–, [Fe4C(CO)12(CuCl)2]2–, [{Fe4Cu2C(CO)12(-Cl)}2]2–, [Fe5C(CO)14(CuC4H8O)]– and [Fe4C(CO)12(CuNCMe)2]