Equilibrium constants for the formation of Wheland complexes from 1,3,5-tris(dialkylamino)benzenes and benzhydrylium ions (Ar2CH+) have been determined photometrically in dichloromethane solution at 20 °C. The Lewis basicity of the ring carbons increases in the series trimorpholinobenzene
Quantification of the Lewis Basicities and Nucleophilicities of 1,3,5-Tris(dialkylamino)benzenes / Micheletti G.; Mayer R.J.; Cino S.; Boga C.; Mazzanti A.; Ofial A.R.; Mayr H.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2021:46(2021), pp. 6347-6357. [10.1002/ejoc.202100939]
Quantification of the Lewis Basicities and Nucleophilicities of 1,3,5-Tris(dialkylamino)benzenes
Micheletti G.Primo
Investigation
;Cino S.Investigation
;Boga C.
Writing – Original Draft Preparation
;Mazzanti A.Investigation
;
2021
Abstract
Equilibrium constants for the formation of Wheland complexes from 1,3,5-tris(dialkylamino)benzenes and benzhydrylium ions (Ar2CH+) have been determined photometrically in dichloromethane solution at 20 °C. The Lewis basicity of the ring carbons increases in the series trimorpholinobenzeneFile in questo prodotto:
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