The rotational spectrum of the molecular complex diacetyl-water has been measured by pulsed jet FTMW spectroscopy. The water molecule acts as an electrofore and induces a dipole moment when combined with non-polar diacetyl. Only one conformer has been observed, corresponding to the global minimum. Its shape is unambiguously established: the water moiety is linked asymmetrically to the organic molecule, it behaves as a proton donor to one of its oxygen atoms and interferes with the internal rotation of the further removed methyl group through a C-HO interaction. Each rotational transition appears as a quintuplet, due to the internal rotation of the two methyl groups, which are non-equivalent in the adduct. From the analysis of the observed splittings, the V3 barriers to the internal rotation of the two methyl groups have been determined to be 3.81(1) and 4.11 (1) kJ/mol, respectively.
Hydrated Complexes of Atmospheric Interest: Rotational Spectrum of Diacetyl-Water
CAMINATI, WALTHER
2009
Abstract
The rotational spectrum of the molecular complex diacetyl-water has been measured by pulsed jet FTMW spectroscopy. The water molecule acts as an electrofore and induces a dipole moment when combined with non-polar diacetyl. Only one conformer has been observed, corresponding to the global minimum. Its shape is unambiguously established: the water moiety is linked asymmetrically to the organic molecule, it behaves as a proton donor to one of its oxygen atoms and interferes with the internal rotation of the further removed methyl group through a C-HO interaction. Each rotational transition appears as a quintuplet, due to the internal rotation of the two methyl groups, which are non-equivalent in the adduct. From the analysis of the observed splittings, the V3 barriers to the internal rotation of the two methyl groups have been determined to be 3.81(1) and 4.11 (1) kJ/mol, respectively.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
