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EnglishThe microwave spectra of three isotopomers of the complex of difluoromethane–xenon (132Xe, 131Xe, 129Xe) have been studied by supersonic jet Fourier transform microwave spectroscopy. A general improvement of the fittings has been obtained with respect to a previous millimeter wave free jet investigation [W. Caminati, J. Phys. Chem. A. 110 (2006) 4359]. In particular, the nuclear quadrupole coupling constants of the 131Xe nucleus in difluoromethane–131Xe have been precisely determined, χaa = 0.941(4), χbb = 0.642(4) and χcc = -1.583(4) MHz, respectively.
| Titolo: | Fourier transform microwave spectrum of difluoromethane–Xe |
| Autore/i: | S. Tang; EVANGELISTI, LUCA; CAMINATI, WALTHER |
| Autore/i Unibo: | |
| Anno: | 2009 |
| Rivista: | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.jms.2009.09.006 |
| Abstract: | The microwave spectra of three isotopomers of the complex of difluoromethane–xenon (132Xe, 131Xe, 129Xe) have been studied by supersonic jet Fourier transform microwave spectroscopy. A general improvement of the fittings has been obtained with respect to a previous millimeter wave free jet investigation [W. Caminati, J. Phys. Chem. A. 110 (2006) 4359]. In particular, the nuclear quadrupole coupling constants of the 131Xe nucleus in difluoromethane–131Xe have been precisely determined, χaa = 0.941(4), χbb = 0.642(4) and χcc = -1.583(4) MHz, respectively. |
| Data prodotto definitivo in UGOV: | 2010-02-09 18:26:38 |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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http://hdl.handle.net/11585/83487
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