The microwave spectra of three isotopomers of the complex of difluoromethane–xenon (132Xe, 131Xe, 129Xe) have been studied by supersonic jet Fourier transform microwave spectroscopy. A general improvement of the fittings has been obtained with respect to a previous millimeter wave free jet investigation [W. Caminati, J. Phys. Chem. A. 110 (2006) 4359]. In particular, the nuclear quadrupole coupling constants of the 131Xe nucleus in difluoromethane–131Xe have been precisely determined, χaa = 0.941(4), χbb = 0.642(4) and χcc = -1.583(4) MHz, respectively.
Fourier transform microwave spectrum of difluoromethane–Xe / S. Tang; L. Evangelisti; W. Caminati. - In: JOURNAL OF MOLECULAR SPECTROSCOPY. - ISSN 0022-2852. - STAMPA. - 258:(2009), pp. 71-74. [10.1016/j.jms.2009.09.006]
Fourier transform microwave spectrum of difluoromethane–Xe
EVANGELISTI, LUCA;CAMINATI, WALTHER
2009
Abstract
The microwave spectra of three isotopomers of the complex of difluoromethane–xenon (132Xe, 131Xe, 129Xe) have been studied by supersonic jet Fourier transform microwave spectroscopy. A general improvement of the fittings has been obtained with respect to a previous millimeter wave free jet investigation [W. Caminati, J. Phys. Chem. A. 110 (2006) 4359]. In particular, the nuclear quadrupole coupling constants of the 131Xe nucleus in difluoromethane–131Xe have been precisely determined, χaa = 0.941(4), χbb = 0.642(4) and χcc = -1.583(4) MHz, respectively.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
