Calix[4]pyrrolidine, is a topological analogue of the chromophore of the pigments of life. An efficient two-step procedure, starting with the condensation between acetone and pyrrole followed by a heterogenous catalytic hydrogenation, has been developed. Many unsuspected aspects demonstrating the influence of the topology on the physicochemical and chemical properties emerged. The simple, symmetric structure showed unique attributes.

Journot, G., Neier, R., Gualandi, A. (2021). Hydrogenation of Calix[4]pyrrole: From the Formation to the Synthesis of Calix[4]pyrrolidine. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021(31), 4444-4464 [10.1002/ejoc.202100620].

Hydrogenation of Calix[4]pyrrole: From the Formation to the Synthesis of Calix[4]pyrrolidine

Gualandi, Andrea
2021

Abstract

Calix[4]pyrrolidine, is a topological analogue of the chromophore of the pigments of life. An efficient two-step procedure, starting with the condensation between acetone and pyrrole followed by a heterogenous catalytic hydrogenation, has been developed. Many unsuspected aspects demonstrating the influence of the topology on the physicochemical and chemical properties emerged. The simple, symmetric structure showed unique attributes.
2021
Journot, G., Neier, R., Gualandi, A. (2021). Hydrogenation of Calix[4]pyrrole: From the Formation to the Synthesis of Calix[4]pyrrolidine. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021(31), 4444-4464 [10.1002/ejoc.202100620].
Journot, Guillaume; Neier, Reinhard; Gualandi, Andrea
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/830699
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