We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices.
Second-Generation Light-Fueled Supramolecular Pump / Canton, Martina; Groppi, Jessica; Casimiro, Lorenzo; Corra, Stefano; Baroncini, Massimo; Silvi, Serena; Credi, Alberto. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 143:29(2021), pp. 10890-10894. [10.1021/jacs.1c06027]
Second-Generation Light-Fueled Supramolecular Pump
Canton, Martina;Groppi, Jessica;Casimiro, Lorenzo;Corra, Stefano;Baroncini, Massimo;Silvi, Serena;Credi, Alberto
2021
Abstract
We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices.| File | Dimensione | Formato | |
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