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EnglishVanadium oxide is the main component of catalysts for selective oxidation reactions, in the form of dispersed oxide over supports, in multi-component mixed oxides, or incorporated inside inert or reactive matrixes. Some examples of the nature of the active site in V oxide-based catalysts and the effect of reaction conditions on its characteristics will be discussed: (a) the nature of the active layer in V/P/O, the catalyst for n-butane oxidation to maleic anhydride; (b) the role of V in V-polyoxometalates for liquid phase oxidations with oxygen, and (c) the nature of the active site in supported V oxide for propane oxidative dehydrogenation and o-xylene oxidation to phthalic anhydride.
| Titolo: | Vanadium oxide-based catalysts: still the basis for research and new findings in selective oxidation |
| Autore/i: | CAVANI, FABRIZIO |
| Autore/i Unibo: | |
| Anno: | 2009 |
| Titolo del libro: | Book of Abstracts Europacat IX Catalysis for a Sustainable World |
| Pagina iniziale: | 107 |
| Pagina finale: | 107 |
| Abstract: | Vanadium oxide is the main component of catalysts for selective oxidation reactions, in the form of dispersed oxide over supports, in multi-component mixed oxides, or incorporated inside inert or reactive matrixes. Some examples of the nature of the active site in V oxide-based catalysts and the effect of reaction conditions on its characteristics will be discussed: (a) the nature of the active layer in V/P/O, the catalyst for n-butane oxidation to maleic anhydride; (b) the role of V in V-polyoxometalates for liquid phase oxidations with oxygen, and (c) the nature of the active site in supported V oxide for propane oxidative dehydrogenation and o-xylene oxidation to phthalic anhydride. |
| Data prodotto definitivo in UGOV: | 22-gen-2010 |
| Appare nelle tipologie: | 4.01 Contributo in Atti di convegno |
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