New chiral BINOL-based phosphate counterions have been synthesized, fully characterized, and employed in the enantioselective gold-catalyzed dearomatization of -naphthols with allenamides. A range of densely functionalized C1-allylated naphthalenones were realized under mild conditions and high levels of chemo-, regio- and stereoselectivity (ee up to 95 %).
Riccardo Pedrazzani, J.A. (2021). New Chiral BINOL‐Based Phosphates for Enantioselective [Au(I)]‐Catalyzed Dearomatization of β‐Naphthols with Allenamides. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 1732-1736 [10.1002/ejoc.202100166].
New Chiral BINOL‐Based Phosphates for Enantioselective [Au(I)]‐Catalyzed Dearomatization of β‐Naphthols with Allenamides
Riccardo PedrazzaniMembro del Collaboration Group
;Juzeng AnMembro del Collaboration Group
;Magda MonariConceptualization
;Marco BandiniConceptualization
2021
Abstract
New chiral BINOL-based phosphate counterions have been synthesized, fully characterized, and employed in the enantioselective gold-catalyzed dearomatization of -naphthols with allenamides. A range of densely functionalized C1-allylated naphthalenones were realized under mild conditions and high levels of chemo-, regio- and stereoselectivity (ee up to 95 %).File in questo prodotto:
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