Nanopowders of Yttrium Aluminium Garnet doped with neodymium (Nd:YAG) were investigated by X-Ray Absorption Fine Structure (XAFS) at the Nd LIII-edge in the 1.3 - 20.8 % doping range. XANES spectra appear similar in the full range of the Nd concentration. However, a significant decrease in the white line intensity of XANES is revealed as the quantity of Nd doping ions increases. Plotting the white line intensity as a function of Nd doping ions reveals two linear trends with two different slopes, identifying a threshold value where the neodymium concentration reaches 5 at.% This experimental finding provides support for the existence of a double doping regime in Nd:YAG nanopowders.
Titolo: | Evidence for a Double Doping Regime in Nd:YAG Nanopowders | |
Autore/i: | GIORGETTI, MARCO; BERRETTONI, MARIO; M. L. Saladino; E. Caponetti | |
Autore/i Unibo: | ||
Anno: | 2009 | |
Rivista: | ||
Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s10853-009-3322-1 | |
Abstract: | Nanopowders of Yttrium Aluminium Garnet doped with neodymium (Nd:YAG) were investigated by X-Ray Absorption Fine Structure (XAFS) at the Nd LIII-edge in the 1.3 - 20.8 % doping range. XANES spectra appear similar in the full range of the Nd concentration. However, a significant decrease in the white line intensity of XANES is revealed as the quantity of Nd doping ions increases. Plotting the white line intensity as a function of Nd doping ions reveals two linear trends with two different slopes, identifying a threshold value where the neodymium concentration reaches 5 at.% This experimental finding provides support for the existence of a double doping regime in Nd:YAG nanopowders. | |
Data prodotto definitivo in UGOV: | 2009-12-10 12:00:24 | |
Appare nelle tipologie: | 1.01 Articolo in rivista |