Pressurized Steam Conversion of Biomass Residues for Liquid Hydrocarbons Generation

Biomass residues are often considered as a resource if conveniently converted in fuel and alternative feedstock for chemical processes, and their conversion into valuable products may occur by different pathways. This work is focused on the thermochemical conversion at moderate temperature and in steam atmosphere, a mild process in comparison to hydrothermal liquefaction, followed by extraction of soluble products in a solvent. Such process has been already applied to various residues and here extended to the case of marc, the residual pomace from wine making, largely produced worldwide. A pressurized batch reactor was used for the quantitative determination of produced solid and liquid fractions, and their qualitative characterization was performed by instrumental analyses. The pressurized steam conversion of marc was effective, providing a yield in liquid fraction, upon extraction in solvent, up to 30% of the raw dried biomass. The use of polar and nonpolar solvent for the extraction of the liquid fraction was inspected. Applied operating conditions, namely residence time in the batch reactor and extraction modality, showed a significant influence on the process performance. In particular, long residence and extraction times and use of nonpolar solvent substantially improved the yield in liquid fraction.