CRIS Current Research Information System
IRIS è la soluzione IT che facilita la raccolta e la gestione dei dati relativi alle attività e ai prodotti della ricerca. Fornisce a ricercatori, amministratori e valutatori gli strumenti per monitorare i risultati della ricerca, aumentarne la visibilità e allocare in modo efficace le risorse disponibili.
EnglishAn amperometric sensor based on Ni1-xAlx(OH)2NO3x×nH2O layered double hydroxide (LDH) has been developed for the electrochem. anal. in one step of two herbicides: glyphosate (N-(phosphonomethyl)glycine, Glyp) and glufosinate ((DL-homoalanine-4-yl)-methylphosphinic acid, Gluf). NiAl-LDH was prepd. by copptn. or by electrodeposition at the Pt electrode surface. Inorg. films were fully characterized by X-ray diffraction, Raman spectroscopy and SEM. Adsorption isotherms of Glyp onto this inorg. lamellar material have been established. Electrocatalytic oxidn. of Glyp and Gluf is possible at the Ni3+ centers of the structure. The electrochem. responses of the NiAl-LDH modified electrode were obtained by cyclic voltammetry and chronoamperometry at 0.49 V/SCE as a function of herbicide concn. in 0.1 M NaOH soln. The electrocatalytic response showed a linear dependence on the Glyp concn. ranging between 0.01 and 0.9 mM with a detection limit of 1 mM and sensitivity 287 mA/M cm2. The sensitivity found for Gluf was lower (178 mA/M cm2).
| Titolo: | Glyphosate and glufosinate detection at electrogenerated NiAl-LDH thin films | |
| Autore/i: | Khenifi A.; Derriche Z.; Forano C.; Prevot V.; Mousty C.; SCAVETTA, ERIKA; BALLARIN, BARBARA; GUADAGNINI, LORELLA; TONELLI, DOMENICA | |
| Autore/i Unibo: | ||
| Anno: | 2009 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.aca.2009.09.023 | |
| Abstract: | An amperometric sensor based on Ni1-xAlx(OH)2NO3x×nH2O layered double hydroxide (LDH) has been developed for the electrochem. anal. in one step of two herbicides: glyphosate (N-(phosphonomethyl)glycine, Glyp) and glufosinate ((DL-homoalanine-4-yl)-methylphosphinic acid, Gluf). NiAl-LDH was prepd. by copptn. or by electrodeposition at the Pt electrode surface. Inorg. films were fully characterized by X-ray diffraction, Raman spectroscopy and SEM. Adsorption isotherms of Glyp onto this inorg. lamellar material have been established. Electrocatalytic oxidn. of Glyp and Gluf is possible at the Ni3+ centers of the structure. The electrochem. responses of the NiAl-LDH modified electrode were obtained by cyclic voltammetry and chronoamperometry at 0.49 V/SCE as a function of herbicide concn. in 0.1 M NaOH soln. The electrocatalytic response showed a linear dependence on the Glyp concn. ranging between 0.01 and 0.9 mM with a detection limit of 1 mM and sensitivity 287 mA/M cm2. The sensitivity found for Gluf was lower (178 mA/M cm2). | |
| Data prodotto definitivo in UGOV: | 2009-11-24 | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
File in questo prodotto:
http://hdl.handle.net/11585/79851
Copyright © 2021