In this report, our work describing the use of spin probes in the field of supramolecular chemistry and how electron spin resonance (EPR) has been used for detecting and identifying supramolecular assemblies is shortly reviewed. Selected examples are reported, including paramagnetic host-guest complexes, self-assembled systems doped with spin probes, spin-labelled macrocycles and open shell mechanically interlocked structures (MIMs) such as rotaxanes, in which the dumbbell, the wheel or both are tagged with nitroxide radicals.
Marco Lucarini (2020). Improving Spin Probe Methodologies to Investigate Supramolecular Assemblies. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 20, 2995-3008 [10.1002/ejoc.201901871].
Improving Spin Probe Methodologies to Investigate Supramolecular Assemblies
Marco Lucarini
Primo
2020
Abstract
In this report, our work describing the use of spin probes in the field of supramolecular chemistry and how electron spin resonance (EPR) has been used for detecting and identifying supramolecular assemblies is shortly reviewed. Selected examples are reported, including paramagnetic host-guest complexes, self-assembled systems doped with spin probes, spin-labelled macrocycles and open shell mechanically interlocked structures (MIMs) such as rotaxanes, in which the dumbbell, the wheel or both are tagged with nitroxide radicals.| File | Dimensione | Formato | |
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Copertina_WILEY_corretta_2021UNIBO_postprint_IRIS-1.pdf
Open Access dal 30/01/2021
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