The present paper reports about a study on the reactivity of Keggin-type P/Mo/V polyoxometalates (POMs) in the oxidation of cyclohexanone to adipic acid with oxygen, in order to find out how the reactivity performance is affected by the POM composition and by reaction conditions. Keggin-type POMs were prepared according to the methods described in the literature. Catalysts prepared were characterized by means of FT-IR spectroscopy.

An alternative method for adipic acid synthesis: the oxidation of cyclohexanone with oxygen in the liquid phase catalysed by Keggin-type polyoxometalates.

RAABOVÁ, KATERINA;BALLARINI, NICOLA;CAVANI, FABRIZIO;FERRONI, LAURA;FRATTINI, ALESSANDRA;MAZZINI, ANDREA;
2009

Abstract

The present paper reports about a study on the reactivity of Keggin-type P/Mo/V polyoxometalates (POMs) in the oxidation of cyclohexanone to adipic acid with oxygen, in order to find out how the reactivity performance is affected by the POM composition and by reaction conditions. Keggin-type POMs were prepared according to the methods described in the literature. Catalysts prepared were characterized by means of FT-IR spectroscopy.
3th Czech-Italian-Spanish Trilateral Meeting on Catalysis and Micro/Meso-Porous Materials CIS-3 Joint with AIZ-2009 IX National Conference on Science and Technology of Zeolites Book of Abstracts
O7
O7
K. Raabova; N. Ballarini; F. Cavani; L. Ferroni; A. Frattini; A. Mazzini; P. Accorinti; S. Alini; P. Babini
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/78454
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact