The present paper reports about a study on the reactivity of Keggin-type P/Mo/V polyoxometalates (POMs) in the oxidation of cyclohexanone to adipic acid with oxygen, in order to find out how the reactivity performance is affected by the POM composition and by reaction conditions. Keggin-type POMs were prepared according to the methods described in the literature. Catalysts prepared were characterized by means of FT-IR spectroscopy.
An alternative method for adipic acid synthesis: the oxidation of cyclohexanone with oxygen in the liquid phase catalysed by Keggin-type polyoxometalates.
RAABOVÁ, KATERINA;BALLARINI, NICOLA;CAVANI, FABRIZIO;FERRONI, LAURA;FRATTINI, ALESSANDRA;MAZZINI, ANDREA;
2009
Abstract
The present paper reports about a study on the reactivity of Keggin-type P/Mo/V polyoxometalates (POMs) in the oxidation of cyclohexanone to adipic acid with oxygen, in order to find out how the reactivity performance is affected by the POM composition and by reaction conditions. Keggin-type POMs were prepared according to the methods described in the literature. Catalysts prepared were characterized by means of FT-IR spectroscopy.File in questo prodotto:
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