Redox active Ni-Pd carbonyl alloy nanoclusters: syntheses, molecular structures and electrochemistry of [Ni22-xPd20+x(CO)48]6-(x= 0.62), [Ni29-xPd6+x(CO)42]6-(x= 0.09) and [Ni29+xPd6-x(CO)42]6-(x= 0.27)