Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intra and in intermolecular processes. The resulting intermediates (nitrogen-centered radicals such as triazenyls, aminyls, or even iminyls) can be conveniently employed in the synthesis of a variety of cyclic and acyclic nitrogen- containing compounds.
From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis / M. Minozzi; D. Nanni; P. Spagnolo. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 15:(2009), pp. 7830-7840. [10.1002/chem.200802710]
From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis
MINOZZI, MATTEO;NANNI, DANIELE;SPAGNOLO, PIERO
2009
Abstract
Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intra and in intermolecular processes. The resulting intermediates (nitrogen-centered radicals such as triazenyls, aminyls, or even iminyls) can be conveniently employed in the synthesis of a variety of cyclic and acyclic nitrogen- containing compounds.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.