Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intra and in intermolecular processes. The resulting intermediates (nitrogen-centered radicals such as triazenyls, aminyls, or even iminyls) can be conveniently employed in the synthesis of a variety of cyclic and acyclic nitrogen- containing compounds.
From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis
MINOZZI, MATTEO;NANNI, DANIELE;SPAGNOLO, PIERO
2009
Abstract
Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intra and in intermolecular processes. The resulting intermediates (nitrogen-centered radicals such as triazenyls, aminyls, or even iminyls) can be conveniently employed in the synthesis of a variety of cyclic and acyclic nitrogen- containing compounds.File in questo prodotto:
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