With the aim of developing a new process for the synthesis of hexamethylene diamine, we studied the gas-phase ammoxidation of n-hexane to unsatured C6 1,6-dinitriles, possible intermediates for hydrogenation to hexamethylene diamine. Catalysts investigated were those that are also active and selective in the similar reaction of propane ammoxidation to acrylonitrile, rutile-type V/Sb and Sn/V/Sb mixed oxides and V/P mixed oxides.
The gas-phase ammoxidation of n-hexane to unsaturated C6 dinitriles, precursors for hexamethylene diamine synthesis / N. Ballarini; A. Battisti; A. Castelli; F. Cavani; C. Lucarelli; P. Marion; P. Righi; C. Spadoni. - STAMPA. - (2008), pp. 73-73. (Intervento presentato al convegno 22nd Conference on the Catalysis of Organic Reactions ORCS Conference tenutosi a Richmond (USA) nel 30 march - 3 april).
The gas-phase ammoxidation of n-hexane to unsaturated C6 dinitriles, precursors for hexamethylene diamine synthesis
BALLARINI, NICOLA;CASTELLI, ALESSANDRO;CAVANI, FABRIZIO;LUCARELLI, CARLO;RIGHI, PAOLO;
2008
Abstract
With the aim of developing a new process for the synthesis of hexamethylene diamine, we studied the gas-phase ammoxidation of n-hexane to unsatured C6 1,6-dinitriles, possible intermediates for hydrogenation to hexamethylene diamine. Catalysts investigated were those that are also active and selective in the similar reaction of propane ammoxidation to acrylonitrile, rutile-type V/Sb and Sn/V/Sb mixed oxides and V/P mixed oxides.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
