The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

Magnabosco, Giulia;Falini, Giuseppe
2019

Abstract

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.
Magnabosco, Giulia; Condorelli, Andrea M M; Rosenberg, Rose; Polishchuk, Iryna; Pokroy, Boaz; Gebauer, Denis; Cölfen, Helmut; Falini, Giuseppe
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/703595
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