The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.
Magnabosco, G., Condorelli, A.M.M., Rosenberg, R., Polishchuk, I., Pokroy, B., Gebauer, D., et al. (2019). Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol. CHEMICAL COMMUNICATIONS, 55(86), 12944-12947 [10.1039/c9cc07087g].
Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol
Magnabosco, Giulia;Falini, Giuseppe
2019
Abstract
The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.File in questo prodotto:
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