Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.
Gualandi A., Rodeghiero G., Faraone A., Patuzzo F., Marchini M., Calogero F., et al. (2019). Allylation of aldehydes by dual photoredox and nickel catalysis. CHEMICAL COMMUNICATIONS, 55(48), 6838-6841 [10.1039/c9cc03344k].
Allylation of aldehydes by dual photoredox and nickel catalysis
Gualandi A.
;Rodeghiero G.;Marchini M.;Calogero F.;Ceroni P.
;Cozzi P. G.
2019
Abstract
Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.File in questo prodotto:
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