The rotational spectra of normal and O-d species of the most stable conformer of chiral 1-(4-fluorophenyl)-1-ethanol have been measured by free jet millimeter-wave absorption spectroscopy. The observed species is stabilized by a O-H interaction and it is at least 1 kcal/mol more stable than the remaining conformers.
B.Velino, M.Satta, W.Caminati (2008). Conformational preferences of chiral molecules: free-jet rotational spectrum of 1-(4-fluorophenyl)-1-ethanol. PHYSICA SCRIPTA, 78, 058106-1-058106-4 [10.1088/0031-8949/78/05/058106].
Conformational preferences of chiral molecules: free-jet rotational spectrum of 1-(4-fluorophenyl)-1-ethanol
VELINO, BIAGIO;CAMINATI, WALTHER
2008
Abstract
The rotational spectra of normal and O-d species of the most stable conformer of chiral 1-(4-fluorophenyl)-1-ethanol have been measured by free jet millimeter-wave absorption spectroscopy. The observed species is stabilized by a O-H interaction and it is at least 1 kcal/mol more stable than the remaining conformers.File in questo prodotto:
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