New arsenic-, antimony- and bismuth-donor reagents are used in a one-pot synthesis of cyclic arsanes, stibanes and bismutanes through a procedure in which the simultaneous formation of three C As, C Sb or C Bi bonds is achieved. At the end of the reaction, the element-donor reagent can be easily re-formed in situ and recycled, as in a catalytic process.
G. Baccolini, C. Boga, M. Mazzacurati, G. Micheletti (2009). The First Flights of a Molecular Shuttle Transporting Elements: Easy One-pot Formation of Organic Cyclic Arsanes, Stibanes and Bismutanes. CHEMISTRY-A EUROPEAN JOURNAL, 15, 597-599 [10.1002/chem.200802007].
The First Flights of a Molecular Shuttle Transporting Elements: Easy One-pot Formation of Organic Cyclic Arsanes, Stibanes and Bismutanes
BACCOLINI, GRAZIANO;BOGA, CARLA;MAZZACURATI, MARZIA;MICHELETTI, GABRIELE
2009
Abstract
New arsenic-, antimony- and bismuth-donor reagents are used in a one-pot synthesis of cyclic arsanes, stibanes and bismutanes through a procedure in which the simultaneous formation of three C As, C Sb or C Bi bonds is achieved. At the end of the reaction, the element-donor reagent can be easily re-formed in situ and recycled, as in a catalytic process.File in questo prodotto:
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