First-principles calculations support the hypothesis that the appropriate spacing between Pd monomers controls the catalytic activity of Pd/Au catalysts in the vinyl acetate formation only if a vinyl surface species is involved in the rate-determining step of the reaction, opening new questions on these relevant catalytic systems. © 2009 The Royal Society of Chemistry.
Mazzone, G., Rivalta, I., Russo, N., Sicilia, E. (2009). The geometric effect in palladium-gold catalysis. Is the coupling the rate-determining step in the vinyl-acetate synthesis?. CHEMICAL COMMUNICATIONS, 14, 1852-1854 [10.1039/b823207e].
The geometric effect in palladium-gold catalysis. Is the coupling the rate-determining step in the vinyl-acetate synthesis?
Rivalta, Ivan;
2009
Abstract
First-principles calculations support the hypothesis that the appropriate spacing between Pd monomers controls the catalytic activity of Pd/Au catalysts in the vinyl acetate formation only if a vinyl surface species is involved in the rate-determining step of the reaction, opening new questions on these relevant catalytic systems. © 2009 The Royal Society of Chemistry.File in questo prodotto:
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