Iron copper zeolite (Fe-Cu-ZSM-5) with aqueous hydrogen peroxide is active for the selective oxidation of methane to methanol. Iron is involved in the activation of the carbon-hydrogen bond, while copper allows methanol to form as the major product. The catalyst is stable, re-usable and activates methane giving >90% methanol selectivity and 10% conversion in a closed catalytic cycle (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5 / Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi; Thetford, Adam; He, Qian; Jenkins, Robert L.; Dimitratos, Nikolaos; Lopez-Sanchez, Jose A.; Dummer, Nicholas F.; Murphy, Damien M.; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Stangland, Eric E.; Kang, Joo; Hagen, Henk; Kiely, Christopher J.; Hutchings, Graham J.*. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 51:21(2012), pp. 5129-5133. [10.1002/anie.201108706]

Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5

Dimitratos, Nikolaos;Lopez-Sanchez, Jose A.;
2012

Abstract

Iron copper zeolite (Fe-Cu-ZSM-5) with aqueous hydrogen peroxide is active for the selective oxidation of methane to methanol. Iron is involved in the activation of the carbon-hydrogen bond, while copper allows methanol to form as the major product. The catalyst is stable, re-usable and activates methane giving >90% methanol selectivity and 10% conversion in a closed catalytic cycle (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
2012
Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5 / Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi; Thetford, Adam; He, Qian; Jenkins, Robert L.; Dimitratos, Nikolaos; Lopez-Sanchez, Jose A.; Dummer, Nicholas F.; Murphy, Damien M.; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Stangland, Eric E.; Kang, Joo; Hagen, Henk; Kiely, Christopher J.; Hutchings, Graham J.*. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 51:21(2012), pp. 5129-5133. [10.1002/anie.201108706]
Hammond, Ceri; Forde, Michael M.; Ab Rahim, Mohd Hasbi; Thetford, Adam; He, Qian; Jenkins, Robert L.; Dimitratos, Nikolaos; Lopez-Sanchez, Jose A.; Dummer, Nicholas F.; Murphy, Damien M.; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Stangland, Eric E.; Kang, Joo; Hagen, Henk; Kiely, Christopher J.; Hutchings, Graham J.*
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/666793
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