Direct and selective: Supported gold-palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Oxidation of methane to methanol with hydrogen peroxide using supported gold-palladium alloy nanoparticles / Ab Rahim, Mohd Hasbi; Forde, Michael M.; Jenkins, Robert L.; Hammond, Ceri; He, Qian; Dimitratos, Nikolaos; Lopez-Sanchez, Jose Antonio; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Murphy, Damien M.; Kiely, Christopher J.; Hutchings, Graham J.*. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 52:4(2013), pp. 1280-1284. [10.1002/anie.201207717]

Oxidation of methane to methanol with hydrogen peroxide using supported gold-palladium alloy nanoparticles

Dimitratos, Nikolaos;Lopez-Sanchez, Jose Antonio;
2013

Abstract

Direct and selective: Supported gold-palladium nanoparticles are active for the oxidation of methane, giving a high selectivity for the formation of methyl hydroperoxide and methanol, using hydrogen peroxide as the oxidant (see picture). The optimal methanol selectivity is achieved by performing the reaction in the presence of hydrogen peroxide that has been generated in situ from hydrogen and oxygen. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
2013
Oxidation of methane to methanol with hydrogen peroxide using supported gold-palladium alloy nanoparticles / Ab Rahim, Mohd Hasbi; Forde, Michael M.; Jenkins, Robert L.; Hammond, Ceri; He, Qian; Dimitratos, Nikolaos; Lopez-Sanchez, Jose Antonio; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Murphy, Damien M.; Kiely, Christopher J.; Hutchings, Graham J.*. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 52:4(2013), pp. 1280-1284. [10.1002/anie.201207717]
Ab Rahim, Mohd Hasbi; Forde, Michael M.; Jenkins, Robert L.; Hammond, Ceri; He, Qian; Dimitratos, Nikolaos; Lopez-Sanchez, Jose Antonio; Carley, Albert F.; Taylor, Stuart H.; Willock, David J.; Murphy, Damien M.; Kiely, Christopher J.; Hutchings, Graham J.*
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/666476
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