In order to obtain a low-toxic and environmentally friendly epoxy system, the novel green curing agent L-Triptophan was used, in combination with the two commercial late curing agents 2-Undecyl-1H-imidazole and 3,3'-(4-Methyl-1,3-phenylene)bis(1,1-dimethylurea), as hardener system for the cross-link of Diglycidyl Ether of Bisphenol A (DGEBA). The thermal behavior of the precursors mixtures was evaluated by dynamic and isothermal Differential Scanning Calorimetry (DSC) and confirmed L-Tryptophan as a possible novel green curing agent for DGEBA. These encouraging results pave the way for a further study of a new class of low-toxic and sustainable curing agent systems for the production of fully bio-based epoxy resins.
Mazzocchetti, L., Merighi, S., Benelli, T., Giorgini, L. (2018). Evaluation of Tryptophan - Late curing agent systems as hardener for epoxy resin. American Institute of Physics Inc. [10.1063/1.5046032].
Evaluation of Tryptophan - Late curing agent systems as hardener for epoxy resin
Mazzocchetti, Laura
;Merighi, Stefano;Benelli, Tiziana;Giorgini, Loris
2018
Abstract
In order to obtain a low-toxic and environmentally friendly epoxy system, the novel green curing agent L-Triptophan was used, in combination with the two commercial late curing agents 2-Undecyl-1H-imidazole and 3,3'-(4-Methyl-1,3-phenylene)bis(1,1-dimethylurea), as hardener system for the cross-link of Diglycidyl Ether of Bisphenol A (DGEBA). The thermal behavior of the precursors mixtures was evaluated by dynamic and isothermal Differential Scanning Calorimetry (DSC) and confirmed L-Tryptophan as a possible novel green curing agent for DGEBA. These encouraging results pave the way for a further study of a new class of low-toxic and sustainable curing agent systems for the production of fully bio-based epoxy resins.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
