The codeposition of PdO particles with a Cu matrix has been investigated with the aim of extending the composite deposition procedure to the preparation of materials potentially capable of catalyzing the low temperature combustion of methane. Cu+PdO composites with a low dispersed phase content were obtained from either basic pyrophosphate or acid sulfate baths. Codeposition of PdO particles with a Cu-Pd alloy matrix was effectively achieved by electrolyzing suspensions of PdO in solutions containing both Cu2+ and Pd 2+ ions, with large [Cu2+] / [Pd2+] ratios. (Cu-Pd) +PdO deposits with 20-25 Pd atom % were obtained in which only 1-2 atom % of Pd were alloyed in the matrix. These (Cu-Pd) +PdO composites were mechanically stable and highly porous throughout their thickness (their pore volume being ca. 60% of the total volume). Their true surface area was some thousands of times higher than their geometric area. © 2010 The Electrochemical Society.
Electrodeposition of Cu+PdO and (Cu-Pd) +PdO composites / Verlato, Enrico*; Cattarin, Sandro; Comisso, Nicola; Gerbasi, Rosalba; Guerriero, Paolo; Musiani, Marco; Vázquez-Gómez, Lourdes. - In: JOURNAL OF THE ELECTROCHEMICAL SOCIETY. - ISSN 0013-4651. - ELETTRONICO. - 157:4(2010), pp. D248-D255. [10.1149/1.3310021]
Electrodeposition of Cu+PdO and (Cu-Pd) +PdO composites
Verlato, Enrico;
2010
Abstract
The codeposition of PdO particles with a Cu matrix has been investigated with the aim of extending the composite deposition procedure to the preparation of materials potentially capable of catalyzing the low temperature combustion of methane. Cu+PdO composites with a low dispersed phase content were obtained from either basic pyrophosphate or acid sulfate baths. Codeposition of PdO particles with a Cu-Pd alloy matrix was effectively achieved by electrolyzing suspensions of PdO in solutions containing both Cu2+ and Pd 2+ ions, with large [Cu2+] / [Pd2+] ratios. (Cu-Pd) +PdO deposits with 20-25 Pd atom % were obtained in which only 1-2 atom % of Pd were alloyed in the matrix. These (Cu-Pd) +PdO composites were mechanically stable and highly porous throughout their thickness (their pore volume being ca. 60% of the total volume). Their true surface area was some thousands of times higher than their geometric area. © 2010 The Electrochemical Society.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.