One of the outstanding features of ionic liquids is their inherently hierarchical structural organization at mesoscopic spatial scales. Recently experimental and computational studies showed the fading of this feature when pressurising. Here we use simulations to show that this effect is not general: appropriate anion choice leads to an obstinate resistance against pressurization.
Communication: Anion-specific response of mesoscopic organization in ionic liquids upon pressurization / Lo Celso Fabrizio, Triolo Alessandro , Gontrani Lorenzo , Russina Olga. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 148:21(2018), pp. 211102-1-211102-4. [10.1063/1.5036588]
Communication: Anion-specific response of mesoscopic organization in ionic liquids upon pressurization
LO CELSO, FABRIZIO;Triolo Alessandro;Gontrani LorenzoMembro del Collaboration Group
;
2018
Abstract
One of the outstanding features of ionic liquids is their inherently hierarchical structural organization at mesoscopic spatial scales. Recently experimental and computational studies showed the fading of this feature when pressurising. Here we use simulations to show that this effect is not general: appropriate anion choice leads to an obstinate resistance against pressurization.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
