The effect of adding ethanol and isopropanol to aqueous solutions of diammonium hydrogen phosphate, used to create a passivating layer of calcium phosphates over marble, was investigated. Thanks to its weakening effect on the hydration sphere of ions in solution, ethanol allowed complete coverage of marble surface by a crack-free and pore-free layer of octacalcium phosphate. Even better results were obtained using isopropanol, because it has lower adsorption affinity to calcite than ethanol. Treatments involving alcohols provided good acid protection and also restored cohesion among calcite grains in weathered marble.

Calcium phosphate coatings for marble conservation: Influence of ethanol and isopropanol addition to the precipitation medium on the coating microstructure and performance / Sassoni, Enrico*; Graziani, Gabriela; Franzoni, Elisa; Scherer, George W.. - In: CORROSION SCIENCE. - ISSN 0010-938X. - ELETTRONICO. - 136:(2018), pp. 255-267. [10.1016/j.corsci.2018.03.019]

Calcium phosphate coatings for marble conservation: Influence of ethanol and isopropanol addition to the precipitation medium on the coating microstructure and performance

Sassoni, Enrico
;
Graziani, Gabriela;Franzoni, Elisa;Scherer, George W.
2018

Abstract

The effect of adding ethanol and isopropanol to aqueous solutions of diammonium hydrogen phosphate, used to create a passivating layer of calcium phosphates over marble, was investigated. Thanks to its weakening effect on the hydration sphere of ions in solution, ethanol allowed complete coverage of marble surface by a crack-free and pore-free layer of octacalcium phosphate. Even better results were obtained using isopropanol, because it has lower adsorption affinity to calcite than ethanol. Treatments involving alcohols provided good acid protection and also restored cohesion among calcite grains in weathered marble.
2018
Calcium phosphate coatings for marble conservation: Influence of ethanol and isopropanol addition to the precipitation medium on the coating microstructure and performance / Sassoni, Enrico*; Graziani, Gabriela; Franzoni, Elisa; Scherer, George W.. - In: CORROSION SCIENCE. - ISSN 0010-938X. - ELETTRONICO. - 136:(2018), pp. 255-267. [10.1016/j.corsci.2018.03.019]
Sassoni, Enrico*; Graziani, Gabriela; Franzoni, Elisa; Scherer, George W.
File in questo prodotto:
File Dimensione Formato  
CORSCI v2.pdf

Open Access dal 14/09/2018

Descrizione: Copertina+Post Print
Tipo: Postprint
Licenza: Licenza per Accesso Aperto. Creative Commons Attribuzione - Non commerciale - Non opere derivate (CCBYNCND)
Dimensione 3.04 MB
Formato Adobe PDF
3.04 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/632511
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 38
  • ???jsp.display-item.citation.isi??? 36
social impact