The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.

Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes

BANDINI, MARCO;EICHHOLZER, ASTRID;KOTRUSZ, PETER;UMANI RONCHI, ACHILLE
2008

Abstract

The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.
M. Bandini; A. Eichholzer; P. Kotrusz; A. Umani-Ronchi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/63022
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