The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.
M. Bandini, A. Eichholzer, P. Kotrusz, A. Umani-Ronchi (2008). Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes. ADVANCED SYNTHESIS & CATALYSIS, 350(4), 531-536 [10.1002/adsc.200700607].
Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes
BANDINI, MARCO;EICHHOLZER, ASTRID;KOTRUSZ, PETER;UMANI RONCHI, ACHILLE
2008
Abstract
The Friedel–Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)4Br2]2 (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.File in questo prodotto:
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