The Raman spectroscopic noncoincidence effect (NCE) describes the frequency separation between the first moments Maniso and Miso of the anisotropic and the isotropic components of the Raman band associated with the vibrational mode in a molecular liquid. The results reported are consistent with with the picture offered by the molecular dynamics simulation of the local solvent organization in acetone water solutions showing a clustering of the solution at all acetone concentrations.
M. Musso, M.G. Giorgini, H. Torii (2008). Microscopic inhomogeneities in liquid mixtures observed through the Raman spectroscopic noncoincidence effect. CHICHESTER : Whitnall R., Chowdhry BZ.
Microscopic inhomogeneities in liquid mixtures observed through the Raman spectroscopic noncoincidence effect
GIORGINI, MARIA GRAZIA;
2008
Abstract
The Raman spectroscopic noncoincidence effect (NCE) describes the frequency separation between the first moments Maniso and Miso of the anisotropic and the isotropic components of the Raman band associated with the vibrational mode in a molecular liquid. The results reported are consistent with with the picture offered by the molecular dynamics simulation of the local solvent organization in acetone water solutions showing a clustering of the solution at all acetone concentrations.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
