Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.
Vlatković, M., Volarić, J., Collins, B.S.L., Bernardi, L., Feringa, B.L.* (2017). Dynamic control over catalytic function using responsive bisthiourea catalysts. ORGANIC & BIOMOLECULAR CHEMISTRY, 15(39), 8285-8294 [10.1039/c7ob01851g].
Dynamic control over catalytic function using responsive bisthiourea catalysts
Bernardi, L.;
2017
Abstract
Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
