Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.
Vlatković, M., Volarić, J., Collins, B., Bernardi, L., Feringa, B. (2017). Dynamic control over catalytic function using responsive bisthiourea catalysts. ORGANIC & BIOMOLECULAR CHEMISTRY, 15(39), 8285-8294 [10.1039/c7ob01851g].
Dynamic control over catalytic function using responsive bisthiourea catalysts
Bernardi, L.;
2017
Abstract
Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
