Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.
Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers / Marco, A. Belen; Cortizo-Lacalle, Diego; Perez-Miqueo, Iã±igo; Valenti, Giovanni; Boni, Alessandro; Plas, Jan; Strutyå ski, Karol; De Feyter, Steven; Paolucci, Francesco; Montes, Mario; Khlobystov, Andrei N.; Melle-Franco, Manuel; Mateo-Alonso, Aurelio. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - ELETTRONICO. - 56:24(2017), pp. 6946-6951. [10.1002/anie.201700271]
Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers
Valenti, Giovanni;Boni, Alessandro;Paolucci, Francesco;
2017
Abstract
Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.| File | Dimensione | Formato | |
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