Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.
Marco, A.B., Cortizo-Lacalle, D., Perez-Miqueo, I., Valenti, G., Boni, A., Plas, J., et al. (2017). Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 56(24), 6946-6951 [10.1002/anie.201700271].
Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers
Valenti, Giovanni;Boni, Alessandro;Paolucci, Francesco;
2017
Abstract
Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.| File | Dimensione | Formato | |
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