Reaction of [Ni-6(CO)(12)](2-) with CCl4 in CH2Cl2 gives the [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-) carbonyl clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties.
Polycarbide nickel clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-) / C. Femoni; M. C. Iapalucci; G. Longoni; S. Zacchini. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 27:(2008), pp. 3157-3159. [10.1039/b803992e]
Polycarbide nickel clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-)
FEMONI, CRISTINA;IAPALUCCI, MARIA CARMELA;LONGONI, GIULIANO;ZACCHINI, STEFANO
2008
Abstract
Reaction of [Ni-6(CO)(12)](2-) with CCl4 in CH2Cl2 gives the [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-) carbonyl clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
