Reaction of [Ni-6(CO)(12)](2-) with CCl4 in CH2Cl2 gives the [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-) carbonyl clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties.
C. Femoni, M. C. Iapalucci, G. Longoni, S. Zacchini (2008). Polycarbide nickel clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-). CHEMICAL COMMUNICATIONS, 27, 3157-3159 [10.1039/b803992e].
Polycarbide nickel clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties: mimicking the supersaturated Ni-C solutions preceding the catalytic growth of CNTs with the structures of [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-)
FEMONI, CRISTINA;IAPALUCCI, MARIA CARMELA;LONGONI, GIULIANO;ZACCHINI, STEFANO
2008
Abstract
Reaction of [Ni-6(CO)(12)](2-) with CCl4 in CH2Cl2 gives the [HNi25(C-2)(4)(CO)(32)](3-) and [Ni-22(C-2)(4)(CO)(28)Cl](3-) carbonyl clusters containing interstitial Ni(eta(2)-C-2)(4) and Ni-2(mu-eta(2)-C-2)(4) acetylide moieties.File in questo prodotto:
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