The role of non-covalent interactions in determining the structure of the 1:1 anisole-water molecular complex has been investigated by the analysis of the rotational spectra of the complex formed by the C6H5OCD3and C6D5OCH3deuterated species of anisole recorded with pulsed jet Fourier transform microwave spectroscopy. The deuteration of the methyl and phenyl hydrogens does not affect the structure and the internal dynamics of the complex, differently from the deuteration of the water moiety, which leads to large isotopic effects (Giuliano et al., 2005).

Effects of deuteration of the methyl and phenyl hydrogens on the rotational spectrum of anisole-water

Giuliano, Barbara M.
Membro del Collaboration Group
;
Melandri, Sonia
Membro del Collaboration Group
;
Caminati, Walther
Membro del Collaboration Group
2017

Abstract

The role of non-covalent interactions in determining the structure of the 1:1 anisole-water molecular complex has been investigated by the analysis of the rotational spectra of the complex formed by the C6H5OCD3and C6D5OCH3deuterated species of anisole recorded with pulsed jet Fourier transform microwave spectroscopy. The deuteration of the methyl and phenyl hydrogens does not affect the structure and the internal dynamics of the complex, differently from the deuteration of the water moiety, which leads to large isotopic effects (Giuliano et al., 2005).
Giuliano, BARBARA MICHELA; Melandri, Sonia; Caminati, Walther
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/611480
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