The role of non-covalent interactions in determining the structure of the 1:1 anisole-water molecular complex has been investigated by the analysis of the rotational spectra of the complex formed by the C6H5OCD3and C6D5OCH3deuterated species of anisole recorded with pulsed jet Fourier transform microwave spectroscopy. The deuteration of the methyl and phenyl hydrogens does not affect the structure and the internal dynamics of the complex, differently from the deuteration of the water moiety, which leads to large isotopic effects (Giuliano et al., 2005).
Giuliano, B.M., Melandri, S., Caminati, W. (2017). Effects of deuteration of the methyl and phenyl hydrogens on the rotational spectrum of anisole-water. JOURNAL OF MOLECULAR SPECTROSCOPY, 337, 86-89 [10.1016/j.jms.2017.04.013].
Effects of deuteration of the methyl and phenyl hydrogens on the rotational spectrum of anisole-water
Giuliano, Barbara M.
Membro del Collaboration Group
;Melandri, SoniaMembro del Collaboration Group
;Caminati, WaltherMembro del Collaboration Group
2017
Abstract
The role of non-covalent interactions in determining the structure of the 1:1 anisole-water molecular complex has been investigated by the analysis of the rotational spectra of the complex formed by the C6H5OCD3and C6D5OCH3deuterated species of anisole recorded with pulsed jet Fourier transform microwave spectroscopy. The deuteration of the methyl and phenyl hydrogens does not affect the structure and the internal dynamics of the complex, differently from the deuteration of the water moiety, which leads to large isotopic effects (Giuliano et al., 2005).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
