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EnglishThe reaction of benzothiadiphosphole 1 with an equimolar mixture of R 1 MgBr and R 2 MgBr gave intermediate A¢, which, after only 4-5 min, was treated with an equimolar amount of R 3 MgBr, giving the asymmetric phosphine PR 1 R 2 R 3 in 45% overall yield (75-80% yield when R 1 ) R 2 and 85-90% yield when R 1 ) R 2 ) R 3 ) and the byproduct 6 in 90% yield. The treatment of 6 with PCl3 quantitatively regenerates the starting reagent 1. Treatment of the phosphines with elemental sulfur gave the corresponding sulfides.
| Titolo: | Highly Atom-Economic One-Pot Formation of Three Different C-P Bonds: General Synthesis of Acyclic Tertiary Phosphine Sulfides | |
| Autore/i: | BACCOLINI, GRAZIANO; BOGA, CARLA; MAZZACURATI, MARZIA | |
| Autore/i Unibo: | ||
| Anno: | 2005 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/jo0502145 | |
| Abstract: | The reaction of benzothiadiphosphole 1 with an equimolar mixture of R 1 MgBr and R 2 MgBr gave intermediate A¢, which, after only 4-5 min, was treated with an equimolar amount of R 3 MgBr, giving the asymmetric phosphine PR 1 R 2 R 3 in 45% overall yield (75-80% yield when R 1 ) R 2 and 85-90% yield when R 1 ) R 2 ) R 3 ) and the byproduct 6 in 90% yield. The treatment of 6 with PCl3 quantitatively regenerates the starting reagent 1. Treatment of the phosphines with elemental sulfur gave the corresponding sulfides. | |
| Data prodotto definitivo in UGOV: | 2005-09-28 19:20:11 | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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http://hdl.handle.net/11585/6048
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