The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.
Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits
SPADA, LORENZO;GOU, QIAN;GEBOES, YANNICK;MELANDRI, SONIA;CAMINATI, WALTHER
2016
Abstract
The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.File in questo prodotto:
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