The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.

Spada, L., Gou, Q., Geboes, Y., Herrebout, W.A., Melandri, S., Caminati, W. (2016). Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 120(27), 4939-4943 [10.1021/acs.jpca.5b12571].

Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits

SPADA, LORENZO;GOU, QIAN;GEBOES, YANNICK;MELANDRI, SONIA;CAMINATI, WALTHER
2016

Abstract

The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.
2016
Spada, L., Gou, Q., Geboes, Y., Herrebout, W.A., Melandri, S., Caminati, W. (2016). Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 120(27), 4939-4943 [10.1021/acs.jpca.5b12571].
Spada, Lorenzo; Gou, Qian; Geboes, Yannick; Herrebout, Wouter A.; Melandri, Sonia; Caminati, Walther
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/599358
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