The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.
Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits / Spada, Lorenzo; Gou, Qian; Geboes, Yannick; Herrebout, Wouter A.; Melandri, Sonia; Caminati, Walther. - In: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY. - ISSN 1089-5639. - STAMPA. - 120:27(2016), pp. 4939-4943. [10.1021/acs.jpca.5b12571]
Rotational Study of Dimethyl Ether-Chlorotrifluoroethylene: Lone Pair···π Interaction Links the Two Subunits
SPADA, LORENZO;GOU, QIAN;GEBOES, YANNICK;MELANDRI, SONIA;CAMINATI, WALTHER
2016
Abstract
The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair···π interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C - O distance of 2.908 Å.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
