The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
Feng, G., Gou, Q., Evangelisti, L., Grabow, J., Caminati, W. (2017). Pulsed jet Fourier transform microwave spectroscopy of the BF3-CO complex. JOURNAL OF MOLECULAR SPECTROSCOPY, 335, 80-83 [10.1016/j.jms.2017.03.001].
Pulsed jet Fourier transform microwave spectroscopy of the BF3-CO complex
FENG, GANG;GOU, QIAN;EVANGELISTI, LUCA;GRABOW, JENS UWE;CAMINATI, WALTHER
2017
Abstract
The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
