The rotational spectra of two conformers of the 1:1 adduct of fluoroacetic acid with water have been assigned by pulsed jet Fourier transform microwave spectroscopy. Their shapes differ according to the trans and cis forms of the fluoroacetic acid moiety. This is in contrast to the rotational spectrum of the monomer, for which the cis form has not been observed. Details of the hydrogen bond, structure, dynamics and energetic features of the two species are given.
Hydrated forms of fluoroacetic acid: A rotational study / Feng, Gang; Gou, Qian; Evangelisti, Luca; Spada, Lorenzo; Blanco, Susana; Caminati, Walther. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 18:34(2016), pp. 23651-23656. [10.1039/c6cp04735a]
Hydrated forms of fluoroacetic acid: A rotational study
FENG, GANG;GOU, QIAN;EVANGELISTI, LUCA;SPADA, LORENZO;BLANCO, SUSANA;CAMINATI, WALTHER
2016
Abstract
The rotational spectra of two conformers of the 1:1 adduct of fluoroacetic acid with water have been assigned by pulsed jet Fourier transform microwave spectroscopy. Their shapes differ according to the trans and cis forms of the fluoroacetic acid moiety. This is in contrast to the rotational spectrum of the monomer, for which the cis form has not been observed. Details of the hydrogen bond, structure, dynamics and energetic features of the two species are given.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
