Significant production of elemental bromine (Br2) was observed for the first time when treating bromide containing solutions at acidic pH, with TiO2photocatalyst, ozone, or a combination thereof. Br2selectivities up to approximately 85 % were obtained and the corresponding bromine mass balance values satisfied. The process is general and may be applied at a laboratory scale for green bromination reactions, or industrially as a cheap, safe, and environmentally sustainable alternative to the currently applied bromine production methods.

Parrino, F., Camera Roda, G., Loddo, V., Palmisano, L. (2016). Elemental Bromine Production by TiO2Photocatalysis and/or Ozonation. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 55(35), 10391-10395 [10.1002/anie.201603635].

Elemental Bromine Production by TiO2Photocatalysis and/or Ozonation

CAMERA RODA, GIOVANNI;
2016

Abstract

Significant production of elemental bromine (Br2) was observed for the first time when treating bromide containing solutions at acidic pH, with TiO2photocatalyst, ozone, or a combination thereof. Br2selectivities up to approximately 85 % were obtained and the corresponding bromine mass balance values satisfied. The process is general and may be applied at a laboratory scale for green bromination reactions, or industrially as a cheap, safe, and environmentally sustainable alternative to the currently applied bromine production methods.
2016
Parrino, F., Camera Roda, G., Loddo, V., Palmisano, L. (2016). Elemental Bromine Production by TiO2Photocatalysis and/or Ozonation. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 55(35), 10391-10395 [10.1002/anie.201603635].
Parrino, Francesco; Camera Roda, Giovanni; Loddo, Vittorio; Palmisano, Leonardo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/575851
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