Composites, materials composed of two or more materials—metallic, organic, or inorganic—usually exhibit the combined physical properties of their component materials. The result is a material that is superior to conventional monolithic materials. Advanced composites are used in a variety of industrial applications and therefore attract much scientific interest. Here the formation of novel carbon-based nanocomposites is described via incorporation of graphene oxide (GO) into the crystal lattice of single crystals of calcite. Incorporation of a 2D organic material into single-crystal lattices has never before been reported. To characterize the resulting nanocomposites, high-resolution synchrotron powder X-ray diffraction, electron microscopy, transmission electron microscopy, fluorescence microscopy and nanoindentation tests are employed. A detailed analysis reveals a layered distribution of GO sheets incorporated within the calcite host. Moreover, the optical and mechanical properties of the calcite host are altered when a carbon-based nanomaterial is introduced into its lattice. Compared to pure calcite, the composite GO/calcite crystals exhibits lower elastic modulus and higher hardness. The results of this study show that the incorporation of a 2D material within a 3D crystal lattice is not only feasible but also can lead to the formation of hybrid crystals exhibiting new properties.

Bioinspired Nanocomposites: Ordered 2D Materials Within a 3D Lattice

DI GIOSIA, MATTEO;FERMANI, SIMONA;PASQUINI, LUCA;ZERBETTO, FRANCESCO;MONTALTI, MARCO;CALVARESI, MATTEO;FALINI, GIUSEPPE;
2016

Abstract

Composites, materials composed of two or more materials—metallic, organic, or inorganic—usually exhibit the combined physical properties of their component materials. The result is a material that is superior to conventional monolithic materials. Advanced composites are used in a variety of industrial applications and therefore attract much scientific interest. Here the formation of novel carbon-based nanocomposites is described via incorporation of graphene oxide (GO) into the crystal lattice of single crystals of calcite. Incorporation of a 2D organic material into single-crystal lattices has never before been reported. To characterize the resulting nanocomposites, high-resolution synchrotron powder X-ray diffraction, electron microscopy, transmission electron microscopy, fluorescence microscopy and nanoindentation tests are employed. A detailed analysis reveals a layered distribution of GO sheets incorporated within the calcite host. Moreover, the optical and mechanical properties of the calcite host are altered when a carbon-based nanomaterial is introduced into its lattice. Compared to pure calcite, the composite GO/calcite crystals exhibits lower elastic modulus and higher hardness. The results of this study show that the incorporation of a 2D material within a 3D crystal lattice is not only feasible but also can lead to the formation of hybrid crystals exhibiting new properties.
Di Giosia, Matteo; Polishchuk, Iryna; Weber, Eva; Fermani, Simona; Pasquini, Luca; Pugno, Nicola M.; Zerbetto, Francesco; Montalti, Marco; Calvaresi, Matteo; Falini, Giuseppe; Pokroy, Boaz
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11585/566467
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