The asymmetric organocatalytic transfer hydrogenation of β-acylamino and β-tert-butyloxycarbonylamino nitroolefins has been successfully realised in excellent enantioselectivities and yields (up to >99% ee, 97% yield) with a simple thiourea catalyst and a Hantzsch ester as hydrogen source, giving a direct access to enantiomerically pure β-amino nitroalkanes. (Figure presented.).

Ferraro, A., Bernardi, L., Fochi, M. (2016). Organocatalytic Enantioselective Transfer Hydrogenation of β-Amino Nitroolefins. ADVANCED SYNTHESIS & CATALYSIS, 358(10), 1561-1565 [10.1002/adsc.201600061].

Organocatalytic Enantioselective Transfer Hydrogenation of β-Amino Nitroolefins

BERNARDI, LUCA;FOCHI, MARIAFRANCESCA
2016

Abstract

The asymmetric organocatalytic transfer hydrogenation of β-acylamino and β-tert-butyloxycarbonylamino nitroolefins has been successfully realised in excellent enantioselectivities and yields (up to >99% ee, 97% yield) with a simple thiourea catalyst and a Hantzsch ester as hydrogen source, giving a direct access to enantiomerically pure β-amino nitroalkanes. (Figure presented.).
2016
Ferraro, A., Bernardi, L., Fochi, M. (2016). Organocatalytic Enantioselective Transfer Hydrogenation of β-Amino Nitroolefins. ADVANCED SYNTHESIS & CATALYSIS, 358(10), 1561-1565 [10.1002/adsc.201600061].
Ferraro, Antonino; Bernardi, Luca; Fochi, Mariafrancesca
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/565791
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