The structure/property relationship of the following CT salts, [M(R2pipdt)2][M(mnt)2] (where R2pipdt = N,N'-dialkylpiperazine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate), [R = Me, M = Pd and Pt ; R = Et, M = Pt ], which were previously characterised, and [Pt(R2pipdt)2][Pt(dtcr)2] [R = Me, Et; dtcr = 4,5-disulfanylcyclopent-4-ene-1,2,3-trionate, known as dithiocroconate] are investigated here. These salts show strong near IR CT bands and semiconducting behaviour.

Paola, D., Maria Laura Mercuri, ., Luciano, M., Luca, P., Marco, S., Angela, S., et al. (2005). Electro-Conducting Properties of Charge-Transfer Salts based on Cationic and Anionic Platinum Dithiolenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005(10), 1829-1835 [10.1002/ejic.200400883].

Electro-Conducting Properties of Charge-Transfer Salts based on Cationic and Anionic Platinum Dithiolenes

SANNA, SAMUELE
2005

Abstract

The structure/property relationship of the following CT salts, [M(R2pipdt)2][M(mnt)2] (where R2pipdt = N,N'-dialkylpiperazine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate), [R = Me, M = Pd and Pt ; R = Et, M = Pt ], which were previously characterised, and [Pt(R2pipdt)2][Pt(dtcr)2] [R = Me, Et; dtcr = 4,5-disulfanylcyclopent-4-ene-1,2,3-trionate, known as dithiocroconate] are investigated here. These salts show strong near IR CT bands and semiconducting behaviour.
2005
Paola, D., Maria Laura Mercuri, ., Luciano, M., Luca, P., Marco, S., Angela, S., et al. (2005). Electro-Conducting Properties of Charge-Transfer Salts based on Cationic and Anionic Platinum Dithiolenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005(10), 1829-1835 [10.1002/ejic.200400883].
Paola, Deplano; Maria Laura Mercuri, ; Luciano, Marchiò; Luca, Pilia; Marco, Salidu; Angela, Serpe; Francesco, Congiu; Sanna, Samuele
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/549455
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