The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzeneCHF3 to indanCHF3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.
Favero, L., Li, W., Spada, L., Evangelisti, L., Visentin, G., Caminati, W. (2015). The Cage Structure of Indan-CHF3 is Based on the Cooperative Effects of C-H⋯π and C-H⋯F Weak Hydrogen Bonds. CHEMISTRY-A EUROPEAN JOURNAL, 21(45), 15970-15973 [10.1002/chem.201502981].
The Cage Structure of Indan-CHF3 is Based on the Cooperative Effects of C-H⋯π and C-H⋯F Weak Hydrogen Bonds
LI, WEIXING;SPADA, LORENZO;EVANGELISTI, LUCA;VISENTIN, GIORGIO;CAMINATI, WALTHER
2015
Abstract
The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzeneCHF3 to indanCHF3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.File in questo prodotto:
Eventuali allegati, non sono esposti
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
