The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzeneCHF3 to indanCHF3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.
The Cage Structure of Indan-CHF3 is Based on the Cooperative Effects of C-H⋯π and C-H⋯F Weak Hydrogen Bonds / Favero, L.B.; Li, W.; Spada, L.; Evangelisti, L.; Visentin, G.; Caminati, W.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 21:45(2015), pp. 15970-15973. [10.1002/chem.201502981]
The Cage Structure of Indan-CHF3 is Based on the Cooperative Effects of C-H⋯π and C-H⋯F Weak Hydrogen Bonds
LI, WEIXING;SPADA, LORENZO;EVANGELISTI, LUCA;VISENTIN, GIORGIO;CAMINATI, WALTHER
2015
Abstract
The structural and energetic features of the CH⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzeneCHF3 to indanCHF3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.File in questo prodotto:
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