A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell
Giorgetti, M., Aquilanti, G., Ciabocco, M., Berrettoni, M. (2015). Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 17(35), 22519-22522 [10.1039/c5cp03580e].
Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures
GIORGETTI, MARCO;CIABOCCO, MICHELA;BERRETTONI, MARIO
2015
Abstract
A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shellFile in questo prodotto:
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