A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell

Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures

GIORGETTI, MARCO;CIABOCCO, MICHELA;BERRETTONI, MARIO
2015

Abstract

A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell
Giorgetti, Marco; Aquilanti, Giuliana; Ciabocco, Michela; Berrettoni, Mario
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/536913
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