The reactions of 4,4'-bipyridine with selected trinuclear triangular copper(II) complexes, [Cu-3(mu(3)-OH)(mu-pz)(3)(RCOO)(2)L-x], [pz = pyrazolate anion, R = CH3(CH2)(n) (2 <= n <= 5); L = H2O, MeOH, EtOH] yielded a series of ID coordination polymers (CPs) based on the repetition of [Cu-3(mu(3)-OH)(mu-pz)(3)] secondary building units joined by bipyridine. The CPs were characterized by conventional analytical methods (elemental analyses, ESI-MS, IR spectra) and single crystal XRD determinations. An unprecedented ID CP, generated through the bipyridine bridging hexanuclear copper clusters moieties, two 1D CPs presenting structural analogies, and two monodimensional tapes having almost exactly superimposable structures, were obtained. In one case, the crystal packing makes evident the presence of small, not-connected pores, accounting for ca. 6% of free cell volume.

Condello, F., Garau, F., Lanza, A., Monari, M., Nestola, F., Pandolfo, L., et al. (2015). Synthesis and structural characterizations of new coordination polymers generated by the interaction between the trinuclear triangular SBU [Cu3(μ3-OH)(μ-pz)3]2+ and 4,4′-Bipyridine. 3°. CRYSTAL GROWTH & DESIGN, 15(10), 4854-4862 [10.1021/acs.cgd.5b00661].

Synthesis and structural characterizations of new coordination polymers generated by the interaction between the trinuclear triangular SBU [Cu3(μ3-OH)(μ-pz)3]2+ and 4,4′-Bipyridine. 3°

MONARI, MAGDA;
2015

Abstract

The reactions of 4,4'-bipyridine with selected trinuclear triangular copper(II) complexes, [Cu-3(mu(3)-OH)(mu-pz)(3)(RCOO)(2)L-x], [pz = pyrazolate anion, R = CH3(CH2)(n) (2 <= n <= 5); L = H2O, MeOH, EtOH] yielded a series of ID coordination polymers (CPs) based on the repetition of [Cu-3(mu(3)-OH)(mu-pz)(3)] secondary building units joined by bipyridine. The CPs were characterized by conventional analytical methods (elemental analyses, ESI-MS, IR spectra) and single crystal XRD determinations. An unprecedented ID CP, generated through the bipyridine bridging hexanuclear copper clusters moieties, two 1D CPs presenting structural analogies, and two monodimensional tapes having almost exactly superimposable structures, were obtained. In one case, the crystal packing makes evident the presence of small, not-connected pores, accounting for ca. 6% of free cell volume.
2015
Condello, F., Garau, F., Lanza, A., Monari, M., Nestola, F., Pandolfo, L., et al. (2015). Synthesis and structural characterizations of new coordination polymers generated by the interaction between the trinuclear triangular SBU [Cu3(μ3-OH)(μ-pz)3]2+ and 4,4′-Bipyridine. 3°. CRYSTAL GROWTH & DESIGN, 15(10), 4854-4862 [10.1021/acs.cgd.5b00661].
Condello, Francesca; Garau, Federica; Lanza, Arianna; Monari, Magda; Nestola, Fabrizio; Pandolfo, Luciano; Pettinari, Claudio
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/536259
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 21
social impact